Ion-exchange membranes for blue energy generation: A short overview focused on nanocomposite

Blue energy can be harvested from salinity gradients between saline water and freshwater by reverse electrodialysis (RED). RED as a conversion technique to generate blue energy has received increasing attention in recent decades. As part of the RED system, ion exchange membranes (IEMs) are key elements to the success of future blue energy generation. However, its suboptimal performance often limits the applications and stagnates the deve­lopment of the technology. The key properties of IEMs include ion exchange capacity, perm­selectivity, and electrical resistance. The enhancement of such physical and electrochemical properties is crucial for studying energy production with acceptable output efficiency on a commercial scale. Recently, many studies have tried blending nanotechnology into the membrane fabrication process. Hybridizing inorganic nanomaterials with an organic polymeric material showed the great potential of improving electrical conductivity and perm­selectivity, as well as other membrane characteristics for power performance. In this short review, recent developments on the IEM synthesis in association with potential nanomaterials are reviewed and raising issues regarding the application and commercialization of RED-based energy production are discussed

Rheological method for alpha test evaluation of developing superplasticizers' performance: Channel flow test

Advance in high-range water-reducing admixture revolutionizes the workability and constructability of conventional vibrated concrete as well as self-consolidating concrete. Its need from construction fields has increased, and consequently a variety of new-type polycarboxylates, base polymers for the admixture, are being formulated in these days. Synthesizing new polymers needs a quick, but reliable, test to evaluate its performance on concrete. The test is also asked for selecting the best applicable brand of them before a test concrete will be mixed. This paper proposes a channel flow test and its usage for the purpose. The proposed procedure for the test includes the mix proportion of a test mortar, the test method, and rheological interpretation of the test results.ope

Introduction on atomic layer deposition for high-k dielectric & high mobility oxide semiconductor thin film transistors

Amorphous oxide semiconductors have been widely studied for the potential use in flat panel displays such as active matrix liquid crystal display (LCD) and Organic light emitting diodes (OLEDs). Since reporting amorphous InGaZnO semiconductor thin film transistor (TFT) in 2003 & 2004, many multi-component oxide semiconductors have been intensively investigated and developed by reactive sputtering method. Very recently, the sputtered InGaZnO TFTs are already adopted in mass-production to fabricate AMOLED TVs. However, there remain several problems such as high mobility & stability issues. Also, virtual and argument reality (VR, AR) applications are rapidly emerging in display markets but the main issues are high resolution and low-voltage driving technologies. Please click Additional Files below to see the full abstract

Seismic evaluation of asymmetric wall systems using a modified three-dimensional capacity spectrum method

This paper proposes a modified three-dimensional capacity spectrum method to efficiently evaluate the seismic behavior of a building structure with asymmetric walls, where twisting is induced due to lateral loading. This method utilizes the demand surfaces and capacity curves that are created based on the inelastic earthquake response and seismic capacity of the asymmetric wall system, respectively. These two parameters are calculated from the displacement, torsional rotation angle and force coordinates of the structure under seismic loading. The seismic retrofit strategy of existing structures can be effectively determined by applying the proposed three-dimensional capacity spectrum method. In this procedure, a new performance point indicating the enhanced performance of the structure can be easily found by the modification of demand surfaces or capacity curves. The seismic evaluation and retrofitting strategies based on this approach are also discussed

Ethanol Extract of the Flower Chrysanthemum morifolium Augments Pentobarbital-Induced Sleep Behaviors: Involvement of Cl− Channel Activation

Dried Chrysanthemum morifolium flowers have traditionally been used in Korea for the treatment of insomnia. This study was performed to investigate whether the ethanol extract of Chrysanthemum morifolium flowers (EFC) enhances pentobarbital-induced sleep behaviors. EFC prolonged sleep time induced by pentobarbital similar to muscimol, a GABAA receptors agonist. EFC also increased sleep rate and sleep time when administrated with pentobarbital at a subhypnotic dosage. Both EFC and pentobarbital increased chloride (Cl−) influx in primary cultured cerebellar granule cells. EFC increased glutamic acid decarboxylase (GAD) expression levels, but had no effect on the expression of α1-, β2-, and γ2-subunits of the GABAA receptor in the hippocampus of a mouse brain. This is in contrast to treatment with pentobarbital, which showed decreased α1-subunit expression and no change in GAD expression. In conclusion, EFC augments pentobarbital-induced sleep behaviors; these effects may result from Cl− channel activation

Start Here When Performing Radiochemical Reactions

Radiation products are present in several fields of knowledge. From the energy field, with nuclear reactors and nuclear batteries, to the medical field, with nuclear medicine and radiation therapy (brachytherapy). Although chemistry works in the same way for radioactive and non-radioactive chemicals, an extra layer of problems is present in the radiochemical counter-part. Reactions can be unpredictable due to several factors. For example, iodine-125 in deposited in a silver wire to create the core of a medical radioactive seed. This core is the sealed forming a radioactive seed that are placed inside the cancer. Several aspects can be discussed in regards to radiation chemistry. For example: are there any competing ions? Each way my reaction is going? Each reaction is more likely to occur? Those are important questions, because, in the case of iodine, a volatile product can be formed causing contamination of laboratory, equipment, personal, and environment. This chapter attempts to create a guideline on how to safely proceed when a new radioactive chemical reaction. It discusses the steps by giving practical examples. The focus is in protecting the operator and the environment. The result can be achieved safely and be reliable contribution to science and society

Evaluation of Left Atrial Volumes Using Multidetector Computed Tomography: Comparison with Echocardiography

OBJECTIVE: To prospectively assess the relationship between the two different measurement methods for the evaluation of left atrial (LA) volume using cardiac multidetector computed tomography (MDCT) and to compare the results between cardiac MDCT and echocardiography. MATERIALS AND METHODS: Thirty-five patients (20 men, 15 women; mean age, 60 years) underwent cardiac MDCT angiography for coronary artery disease. The LA volumes were measured using two different methods: the two dimensional (2D) length-based (LB) method measured along the three-orthogonal planes of the LA and the 3D volumetric threshold-based (VTB) method measured according to the threshold 3D segmentation of the LA. The results obtained by cardiac MDCT were compared with those obtained by echocardiography. RESULTS: The LA end-systolic and end-diastolic volumes (LAESV and LAEDV) measured by the 2D-LB method correlated well with those measured by the 3D-VTB method using cardiac MDCT (r = 0.763, r = 0.786, p = 0.001). However, there was a significant difference in the LAESVs between the two measurement methods using cardiac MDCT (p < 0.05). The LAESV measured by cardiac MDCT correlated well with measurements by echocardiography (r = 0.864, p = 0.001), however with a significant difference (p < 0.01) in their volumes. The cardiac MDCT overestimated the LAESV by 22% compared to measurements by echocardiography. CONCLUSION: A significant correlation was found between the two different measurement methods for evaluating LA volumes by cardiac MDCT. Further, cardiac MDCT correlates well with echocardiography in evaluating the LA volume. However, there are significant differences in the LAESV between the two measurement methods using cardiac MDCT and between cardiac MDCT and echocardiographyope

Accelerating ID-based Encryption based on Trapdoor DL using Pre-computation

The existing identity-based encryption (IBE) schemes based on pairings require pairing computations in encryption or decryption algorithm and it is a burden to each entity which has restricted computing resources in mobile computing environments. An IBE scheme (MY-IBE) based on a trapdoor DL group for RSA setting is one of good alternatives for applying to mobile computing environments. However, it has a drawback for practical use, that the key generation algorithm spends a long time for generating a user\u27s private key since the key generation center has to solve a discrete logarithm problem. In this paper, we suggest a method to reduce the key generation time of the MY-IBE scheme, applying modified Pollard rho algorithm using significant pre-computation (mPAP). We also provide a rigorous analysis of the mPAP for more precise estimation of the key generation time and consider the parallelization and applying the tag tracing technique to reduce the wall-clock running time of the key generation algorithm. Finally, we give a parameter setup method for an efficient key generation algorithm and estimate key generation time for practical parameters from our theoretical analysis and experimental results on small parameters. Our estimation shows that it takes about two minutes using pre-computation for about 50 days with 27 GB storage to generate one user\u27s private key using the parallelized mPAP enhanced by the tag tracing technique with 100 processors

Inhibitory Effect of Inflexinol on Nitric Oxide Generation and iNOS Expression via Inhibition of NF-κB Activation

Inflexinol, an ent-kaurane diterpenoid, was isolated from the leaves of Isodon excisus. Many diterpenoids isolated from the genus Isodon (Labiatae) have antitumor and antiinflammatory activities. We investigated the antiinflammatory effect of inflexinol in RAW 264.7 cells and astrocytes. As a result, we found that inflexinol (1, 5, 10 μM) suppressed the expression of inducible nitric oxide synthase (iNOS) and cyclooxygenase-2 (COX-2) as well as the production of nitric oxide (NO) in LPS-stimulated RAW 264.7 cells and astrocytes. Consistent with the inhibitory effect on iNOS and COX-2 expression, inflexinol also inhibited transcriptional and DNA binding activity of NF-κB via inhibition of IκB degradation as well as p50 and p65 translocation into nucleus. These results suggest that inflexinol inhibits iNOS and COX-2 expression through inhibition of NF-κB activation, thereby inhibits generation of inflammatory mediators in RAW 264.7 cells and astrocytes, and may be useful for treatment of inflammatory diseases

Strain-gradient-induced magnetic anisotropy in straight-stripe mixed-phase bismuth ferrites: An insight into flexomagnetic phenomenon

Implementation of antiferromagnetic compounds as active elements in spintronics has been hindered by their insensitive nature against external perturbations which causes difficulties in switching among different antiferromagnetic spin configurations. Electrically-controllable strain gradient can become a key parameter to tune the antiferromagnetic states of multiferroic materials. We have discovered a correlation between an electrically-written straight-stripe mixed-phase boundary and an in-plane antiferromagnetic spin axis in highly-elongated La-5%-doped BiFeO$_{3}$ thin films by performing polarization-dependent photoemission electron microscopy in conjunction with cluster model calculations. Model Hamiltonian calculation for the single-ion anisotropy including the spin-orbit interaction has been performed to figure out the physical origin of the link between the strain gradient present in the mixed phase area and its antiferromagnetic spin axis. Our findings enable estimation of the strain-gradient-induced magnetic anisotropy energy per Fe ion at around 5$\times$10$^{-12}$ eV m, and provide a new pathway towards an electric-field-induced 90$^{\circ}$ rotation of antiferromagnetic spin axis at room temperature by flexomagnetism.Comment: 32 pages, 5 figure